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Selas Fluid
A Member of the Linde
Engineering Division
Five Sentry Parkway East
Blue Bell,
PA 19422
United States
Phone: 610-834-0300
Fax: 610-834-0473
www.selasfluid.com

Flame Based Thermal Oxidizers – Aqueous Waste Streams

Aqueous waste streams are generated by many processes and are commonly treated by biological methods. However, when biological treatment is not technically or economically practical then incineration is the best alternative. Over the past fifty years, Selas Fluid has supplied over 35 T-Thermal liquid incinerators handling this special class of waste, meeting the required emission limits and providing high online availability. We have units in operation from 1 million (0.3MW) to over 120 million Btu/hr (35MW).

Incineration of waste streams that are basically salt brines, aqueous liquids containing organic contaminates and inorganic salts or metals offer a particular challenge. The foremost consideration is the complete destruction of organic components. The presence of inorganic metals, most typically alkalis, requires the designer to consider reactions within the gas phase as well as reactions between the formed salts and refractory linings.

Typical applications include:

  • Spent Caustic from Ethylene Plants
  • Refinery Wastes
  • Pharmaceutical Plant Wastes
  • Agricultural Chemical Plant Waste
  • Bio-diesel Plant Waste
 

Flame Based Thermal Oxidizers – Aqueous Waste Streams - The Technology

Most of the alkaline metal group form salts during the incineration process with melting points lower than that required for complete combustion of the organics. These molten salts are corrosive to and reactive with common refractory materials. Selection of the proper operating temperature and lining material is crucial to obtaining acceptable online availability for the plant.

Sub-X Salt System With Waste Heat RecoveryMost of the salts collect on the walls of the unit, necessitating allowance for continuous removal of the accumulated molten mass. The incinerator is “downfired” into a cylindrical, vertically oriented vessel. Exhaust from the incinerator chamber is directed into a submerged quench (Sub-X®) vessel. The Sub-X quench design is particularly efficient for this process, rapidly cooling the gases, dissolving most of the salt into the quench liquor due to high agitation, and providing initial cleaning of the gases.

A portion of the salts formed in the incinerator remain suspended within the gas stream at the outlet of the quench, and Selas Fluid has developed the expertise to meet the most stringent air quality standards.
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Thermal Oxidizer to Treat Aqueous Waste

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